What is Free T4?
Free T4 (Free Thyroxine) measures the unbound, metabolically active form of thyroxine in the blood. While most T4 is bound to carrier proteins (thyroid-binding globulin, transthyretin, and albumin), only the free fraction can enter cells and exert physiologic effects.
Free vs. Bound T4
Understanding the distinction between free and bound T4 is essential:
- Total T4: 99.97% bound to proteins (mainly TBG), 0.03% free
- Free T4: Only the 0.03% unbound fraction - this is what enters cells and regulates metabolism
- Protein binding: TBG binds ~75%, transthyretin ~15%, albumin ~10% of circulating T4
- Dynamic equilibrium: Bound and free T4 exist in equilibrium; as free T4 is consumed, bound T4 is released
T4 as Prohormone for T3
T4 functions primarily as a reservoir and prohormone for the more potent T3:
- Peripheral conversion: 80% of circulating T3 comes from T4 deiodination in peripheral tissues (liver, kidney, muscle)
- Type 1 deiodinase (D1): Converts T4 to T3 in liver and kidney
- Type 2 deiodinase (D2): Converts T4 to T3 locally in brain, pituitary, brown fat
- Reverse T3: Alternative pathway produces inactive rT3 (increased in illness, fasting)
- Potency difference: T3 is 3-4 times more metabolically active than T4
Levothyroxine is Synthetic T4
Levothyroxine (Synthroid, Levoxyl) is synthetic T4 and the standard treatment for hypothyroidism:
- Conversion to T3: Body converts levothyroxine to active T3 via peripheral deiodinases
- Long half-life: T4 half-life ~7 days allows once-daily dosing and steady plasma levels
- Dose monitoring: Monitor TSH (not Free T4) for dose adjustment; TSH more sensitive
- Steady state: Takes 6-8 weeks after dose change for TSH to equilibrate
Clinical Use
Free T4 is ordered alongside TSH for complete thyroid assessment:
- After abnormal TSH: Confirms thyroid dysfunction and distinguishes subclinical from overt disease
- Monitoring treatment: Tracks response to levothyroxine or antithyroid drugs (TSH is primary target)
- Central hypothyroidism: Low Free T4 with inappropriately low/normal TSH suggests pituitary failure
- Non-thyroidal illness: Helps distinguish sick euthyroid syndrome from true hypothyroidism